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RAS PhysicsКристаллография Crystallography Reports

  • ISSN (Print) 0023-4761
  • ISSN (Online) 3034-5510

The Role of Chemical Pressure in the Formation of the Structure and Barocaloric Properties of Complex Fluorides and Oxyfluorides

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PII
10.31857/S0023476123600477-1
DOI
10.31857/S0023476123600477
Publication type
Status
Published
Authors
I. N. Flerov
  • Affiliation: Institute of Chemistry, Far Eastern Branch, Vladivostok, Russia
Volume/ Edition
Volume 68 / Issue number 5
Pages
776-789
Abstract
The role of chemical pressure as an effective tool in the processes of formation of initial and distorted (as a result of structural transformations) phases, thermodynamic properties, and direct and inverse barocaloric effects in some complex oxyfluorides and fluorides with octahedral, tetrahedral, and spherical anion and cation groups in the structure has been studied. It is found that, due to the small temperature hysteresis and high baric sensitivity of materials, the maximum values of absolute and integral barocaloric characteristics can be implemented at low pressures. Correspondingly, the temperature range of reversibility of thermodynamic cycles based on fluorides/oxyfluorides as solid-state coolants can be expanded.
Keywords
Date of publication
15.09.2025
Year of publication
2025
Number of purchasers
0
Views
15

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