Synthesis features of LiRF4 (R = Er–Lu) nanoparticles by the high-temperature co-precipitation method and their photoluminescent properties

Koshelev, A. V.

doi:10.31857/S0023476124020168

PII

10.31857/S0023476124020168-1

DOI

10.31857/S0023476124020168

Publication type

Article

Status

Published

Authors

A. V. Koshelev

Affiliation: Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics of NRC “Kurchatov Institute”

Volume/ Edition

Volume 69 / Issue number 2

Pages

319-329

Abstract

Nanoparticles of LiRF₄ (R = Y, Yb, Lu), activated with Yb³⁺/Er³⁺ and Yb³⁺/Tm³⁺ ions, were obtained by the high-temperature co-precipitation method. The influence of the precursor molar ratio and the cationic composition of matrices on their dimensionality and morphology was studied. A method for the heterogeneous crystallization of these compounds using LiYF₄ nanoseeds was optimized, which opens up opportunities for controlled synthesis of LiRF₄ nanoparticles with controllable characteristics. Among the studied objects, LiYF₄@LiYbF₄:Tm³⁺@LiYF₄ nanoparticles demonstrate the most intense anti-Stokes photoluminescence in the UV (λ = 362 nm) and blue (λ = 450 nm) ranges, exceeding similar indicators for β-NaYF₄:Yb³⁺/Tm³⁺@NaYF₄ particles. LiYF₄@LiLuF₄:Yb³⁺/Er³⁺@LiYF₄ nanoparticles are the most efficient converters of IR radiation in the λ = 1530 nm range among the investigated isostructural matrices and exhibit similar spectral-luminescent properties to the β-NaYF₄:Yb₃+/Er₃+@NaYF₄ compound with an equivalent degree of codoping. The obtained results allow considering LiYF₄@LiYbF₄:Tm³⁺@LiYF₄ and LiYF₄@LiLuF₄:Yb³⁺/Er³⁺@LiYF₄ nanoparticles as a real alternative to the most widely used phosphors based on the hexagonal matrix β-NaYF₄ for photonics and biotechnology applications.

Keywords

Date of publication

15.09.2025

Year of publication

2025

Number of purchasers

Views

References

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GOST	Koshelev A. Synthesis features of LiRF₄ (R = Er–Lu) nanoparticles by the high-temperature co-precipitation method and their photoluminescent properties // Crystallography Reports. – 2024. – V. 69. – Issue number 2 C. 319-329 . URL: https://crystallographyras.ru/10-31857-s0023476124020168-1/?version_id=110135. DOI: 10.31857/S0023476124020168
MLA	Koshelev, A. V "Synthesis features of LiRF₄ (R = Er–Lu) nanoparticles by the high-temperature co-precipitation method and their photoluminescent properties." Crystallography Reports. 69.2 (2024).:319-329. DOI: 10.31857/S0023476124020168
APA	Koshelev A. (2024). Synthesis features of LiRF₄ (R = Er–Lu) nanoparticles by the high-temperature co-precipitation method and their photoluminescent properties. Crystallography Reports. vol. 69, no. 2, pp.319-329 DOI: 10.31857/S0023476124020168

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Synthesis features of LiRF₄ (R = Er–Lu) nanoparticles by the high-temperature co-precipitation method and their photoluminescent properties

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Synthesis features of LiRF₄ (R = Er–Lu) nanoparticles by the high-temperature co-precipitation method and their photoluminescent properties