- PII
- 10.31857/S0023476124050123-1
- DOI
- 10.31857/S0023476124050123
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 69 / Issue number 5
- Pages
- 858-865
- Abstract
- The photopolymerization of Langmuir-Schaefer films of diacetylene N-arylcarbamate symmetrical molecules containing different numbers of methylene groups in the molecules was studied. The result of diyne films UV irradiation was the effective transition of the films into the stable state of blue phase polydiacetylene. The number of CH2 groups in the molecules affected the efficiency of the monomers film transition into the polymer and the conjugation length of the polymer chains. Studying the morphology of the films using scanning electron microscopy showed the horizontal position of diyne molecules on the substrates in the state of domains, the sizes of which depended on the number of CH2 groups in the molecules.
- Keywords
- Date of publication
- 15.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 7
References
- 1. Wegner G. // Z. Naturforsch. B. 1969. V. 24. P. 824. https://doi.org/10.1515/znb-1969-0708
- 2. Vinogradov G.A. // Russ. Chem. Rev. 1984. V. 53. № 1. P. 77.
- 3. Polydiacetylenes: Synthesis, Structure and Electronic Properties / Eds. Bloor D., Chance R. 1985. 409 p.
- 4. Kruchinin V.N., Repinsky S.M., Sveshnikova L.L // Thin Solid Films. 1994. V. 240. P. 131.
- 5. Kim T., Ye Q., Sun I. et al. // Langmuir. 1996. V. 12. P. 6065. https://doi.org/10.1021/la960810h
- 6. Langmuir-Blodgett Films / Ed. Roberts G. New York: Plenum Press, 1990. P. 425.
- 7. Tieke B., Lieser G., Wegner G. // J. Polym. Sci. Polym. Chem. Ed. 1979. V. 17. P. 1631.
- 8. Tamura H., Mino N., Ogawa K. // Thin Solid Films. 1989. V. 179. P. 33.
- 9. Patel G.N., Khanna Y.P., Ivory D.M. et al. // J. Polym. Sci. Polym. Phys. Ed. 1979. V. 17. P. 899. https://doi.org/10.1002/pol.1979.180170513
- 10. Zhong L., Zhu X., Duan P., Liu M. // J. Phys. Chem. B. 2010. V. 114. P. 8871. https://doi.org/10.1021/jp1020565
- 11. Alekseev A., Ihalainen P., Ivanov A. et al. // Thin Solid Films. 2016. V. 612. P. 463. https://dx.doi.org/10.1016/j.tsf.2016.06.044
- 12. Alekseev A.S., Ivanov A.B., Klechkovskaya V.V. et al. // Rev. Adv. Chem. 2023. V. 13. № 3. P. 265. https://doi.org/10.1134/S263482762360010X
- 13. Marinichev A.N., Vyaz’min S. Yu., Domnin I.N. // Russ. J. Appl. Chem. 2005. V. 78. № 10. P. 1662.
- 14. Alekseev A.S., Vyaz’min S. Yu., Ivanov A.B. et al. // Crystallography Reports. 2024. V. 69. № 4. P. 541 https://doi.org/10.1134/S1063774524600455
