Anhydrous natural sulfates with alkali cations: structural features, comparative crystal chemistry, and genetic mineralogy

PII
S0023476125020034-1
DOI
10.31857/S0023476125020034
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 70 / Issue number 2
Pages
225-243
Abstract
This review presents data on the crystal chemistry and genetic mineralogy of all known natural anhydrous sulfates with species-defining alkali cations—Na or/and K (61 mineral species, 48 structural types). These minerals are primarily associated with two genetic mineralization environments: volcanic fumaroles and evaporites. Both environments are characterized by low (atmospheric) pressure but differ significantly in temperature and crystallization mechanisms. Based on structural classification, the studied minerals are divided into two major groups: (1) those with an anionic motif consisting solely of SO₄ tetrahedra (sometimes including additional anions such as F, Cl, or CO₃), and (2) those with heteropolyhedral anionic motifs composed of SO₄ tetrahedra and polyhedra of cations with relatively high-strength characteristics (e.g., Mg, Mn, Zn, Cu, Fe, V, Al, Bi, Mo, As, Te, and occasionally Ca). This classification aligns with genetic types: the first group predominates in evaporitic environments, while the second group is more common in fumarolic settings. A clear positive correlation has been established between the degree of polymerization of the heteropolyhedral anionic motif and the number of minerals in which such motifs occur. Specifically, 18 minerals exhibit frameworks or pseudo-frameworks of varying topologies, 11 minerals feature layered motifs, eight minerals contain chain-like motifs, and only one mineral contains isolated heteropolyhedral complexes. Additionally, the review discusses various types of solid-solution breakdown and other solid-state transformations in high-temperature sulfates with aphthitalite-like structures from volcanic fumaroles.
Keywords
Date of publication
26.07.2025
Number of purchasers
0
Views
42

References

  1. 1. Rudnick R.L., Gao S. // Treatise on Geochemistry / Eds. Holland H.D., Turekian K.K. 2003. V. 3. https://doi.org/10.1016/B0-08-043751-6/03016-4
  2. 2. Hawthorne F.C., Krivovichev S.V., Burns P.C. // Rev. Mineral. Geochem. 2000. V. 40. P. 1. https://doi.org/10.2138/rmg.2000.40.1
  3. 3. Pushcharovsky D.Yu. // Crystallography Reports. 2023. V. 68 (Suppl. 1). P. S206. https://doi.org/10.1134/S1063774523601545
  4. 4. Chukanov N.V., Shchipalkina N.V., Shendrik R.Yu. et al. // Minerals. 2022. V. 12. P. 1456. https://doi.org/10.3390/min12111456
  5. 5. Пеков И.В., Чуканов Н.В., Щербаков В.Д. и др. // Записки Рос. минерал. о-ва. 2024. Т. 153. С. 12. https://doi.org/10.31857/S0869605524010023
  6. 6. Hawthorne F.C., Ferguson R.B. // Can. Mineral. 1975. V. 13. P. 181. https://pubs.geoscienceworld.org/mac/canmin/article-abstract/13/2/181/11030/Anhydrous-sulphates-I-Refinement-of-the-crystal
  7. 7. Зубкова Н.В., Пеков И.В., Ксенофонтов Д.А. и др. // Докл. РАН. 2018. Т. 479. С. 63. https://doi.org/10.7868/S0869565218010152
  8. 8. Pekov I.V., Shchipalkina N.V., Zubkova N.V. et al. // Can. Mineral. 2019. V. 57. P. 885. https://doi.org/10.3749/canmin.1900050
  9. 9. Okada K., Ossaka J. // Acta Cryst. В. 1980. V. 36. P. 919. https://doi.org/10.1107/S0567740880004852
  10. 10. Shchipalkina N.V., Pekov I.V., Chukanov N.V. et al. // Can. Mineral. 2020. V. 58. P. 167. https://doi.org/10.3749/canmin.1900076
  11. 11. Filatov S.K., Shablinskii A.P., Vergasova L.P. et al. // Mineral. Mag. 2019. V. 83. P. 569. https://doi.org/10.1180/mgm.2018.170
  12. 12. Tissot R.G., Rodriguez M.A., Sipola D.L., Voigt J.A. // Powder Diffraction. 2001. V. 16. P. 92. https://doi.org/10.1154/1.1370567
  13. 13. Мурашко М.Н., Пеков И.В., Кривовичев С.В. и др. // Записки Рос. минерал. о-ва. 2012. Т. 141. С. 36.
  14. 14. Graeber E.J., Rosenzweig A. // Am. Mineral. 1971. V. 56. P. 1917.
  15. 15. Balić-Žunić T., Garavelli A., Acquafredda P. et al. // Mineral. Mag. 2009. V. 73. P. 51. https://doi.org/10.1180/minmag.2009.073.1.51
  16. 16. Araki T., Zoltai T. // Am. Mineral. 1967. V. 52. P. 1272.
  17. 17. Siidra O.I., Lukina E.A., Nazarchuk E.V. et al. // Mineral. Mag. 2018. V. 82. P. 257. https://doi.org/10.1180/minmag.2017.081.037
  18. 18. Mereiter K. // Neues Jahr. Mineral. Mh. 1979. P. 182.
  19. 19. Oelkrug H., Brückel T., Hohlwein D. et al. // Phys. Chem. Mineral. 1988. V. 16. P. 246. https://doi.org/10.1007/BF00220692
  20. 20. Pekov I.V., Zelenski M.E., Zubkova N.V. et al. // Mineral. Mag. 2012. V. 76. P. 673. https://doi.org/10.1180/minmag.2012.076.3.16
  21. 21. Pekov I.V., Zubkova N.V., Galuskina I.O. et al. // Mineral. Mag. 2022. V. 86. P. 557. https://doi.org/10.1180/mgm.2021.95
  22. 22. Balić-Žunić T., Pamato M.G., Nestola F. // Acta Cryst. Е. 2020. V. 76. P. 785. https://doi.org/10.1107/S2056989020005873
  23. 23. Shablinskii A.P., Filatov S.K., Krivovichev S.V. et al. // Mineral. Mag. 2021. V. 85. P. 233. https://doi.org/10.1180/mgm.2021.9
  24. 24. Shchipalkina N.V., Pekov I.V., Koshlyakova N.N. et al. // Mineral. Mag. 2024. V. 88. P. 49. https://doi.org/10.1180/mgm.2023.85
  25. 25. Filatov S.K., Shablinskii A.P., Krivovichev S.V. et al. // Mineral. Mag. 2020. V. 84. P. 691. https://doi.org/10.1180/mgm.2020.53
  26. 26. Nazarchuk E.V., Siidra O.I., Agakhanov A.A. et al. // Mineral. Mag. 2018. V. 82. P. 1233. https://doi.org/10.1180/minmag.2017.081.089
  27. 27. Gorelova L.A., Vergasova L.P., Krivovichev S.V. et al. // Eur. J. Mineral. 2016. V. 28. P. 677. https://doi.org/10.1127/ejm/2016/0028-2530
  28. 28. Siidra O.I., Nazarchuk E.V., Zaitsev A.N., Shilovskikh V.V. // Mineral. Mag. 2020. V. 84. P. 153. https://doi.org/10.1180/mgm.2019.68
  29. 29. Siidra O.I., Nazarchuk E.V., Zaitsev A.N., Vlasenko N.S. // Mineral. Mag. 2020. V. 84. P. 283. https://doi.org/10.1180/mgm.2019.69
  30. 30. Зубкова Н.В., Пеков И.В., Агаханов А.А. и др. // Кристаллография. 2021. Т. 66. С. 51. https://doi.org/10.31857/S0023476121010239
  31. 31. Reynaud M., Barpanda P., Rousse G. et al. // Solid State Sci. 2012. V. 14. P. 15. https://doi.org/10.1016/j.solidstatesciences.2011.09.004
  32. 32. Pekov I.V., Krzhizhanovskaya M.G., Yapaskurt V.O. et al. // Eur. J. Mineral. 2015. V. 27. P. 575. https://doi.org/ 10.1127/ejm/2015/0027-2457
  33. 33. Pekov I.V., Britvin S.N., Bulakh M.O. et al. // Eur. J. Mineral. 2024. V. 36. P. 917. https://doi.org/ 10.5194/ejm-36-917-2024
  34. 34. Pekov I.V., Zubkova N.V., Britvin S.N. et al. // Eur. J. Mineral. 2016. V. 28. P. 53. https://doi.org/10.1127/ejm/2015/0027-2471
  35. 35. Pekov I.V., Zelenski M.E., Zubkova N.V. et al. // Am. Mineral. 2012. V. 97. P. 1788. https://doi.org/10.2138/am.2012.4104
  36. 36. Schneider W. // Neues Jb. Mineral. Mh. 1967. P. 284.
  37. 37. Schneider W. // Neues Jb. Mineral. Mh. 1969. P. 58.
  38. 38. Demartin F., Gramaccioli C.M., Campostrini I. et al. // Am. Mineral. 2010. V. 95. P. 382. https://doi.org/ 10.2138/am.2010.3337
  39. 39. Siidra O.I., Nazarchuk E.V., Lukina E.A. et al. // Mineral. Mag. 2018. V. 82. P. 1079. https://doi.org/ 10.1180/minmag.2017.081.084
  40. 40. Giacovazzo C., Scandale E., Scordari F. // Z. Kristallogr. 1976. V. 144. P. 226. https://doi.org/10.1524/zkri.1976.144.1-6.226
  41. 41. Demartin F., Campostrini I., Castellano C. et al. // Mineral. Mag. 2012. V. 76. P. 2773. https://doi.org/10.1180/minmag.2012.076.7.10
  42. 42. Scordari F., Stasi F. // Neues Jb. Mineral. Mh. 1990. P. 241.
  43. 43. Siidra O.I., Borisov A.S., Lukina E.A. // Phys. Chem. Min. 2019. V. 46. P. 403. https://doi.org/10.1007/s00269-018-1011-9
  44. 44. Siidra O.I., Nazarchuk E.V., Zaitsev A.N. et al. // Eur. J. Mineral. 2017. V. 29. P. 499. https://doi.org/10.1127/ejm/2017/0029-2619
  45. 45. Starova G.L., Filatov S.K., Fundamensky V.S., Vergasova L.P. // Mineral. Mag. 1991. V. 55. P. 613. https://doi.org/10.1180/minmag.1991.055.381.14
  46. 46. Pekov I.V., Zubkova N.V., Agakhanov A.A. et al. // Eur. J. Mineral. 2018. V. 30. P. 593. https://doi.org/10.1127/ejm/2018/0030-2725
  47. 47. Pekov I.V., Zubkova N.V., Yapaskurt V.O. et al. // Can. Mineral. 2014. V. 52. P. 699. https://doi.org/10.3749/canmin.1400018
  48. 48. Pekov I.V., Zubkova N.V., Agakhanov A.A. et al. // Can. Mineral. 2020. V. 58. P. 625. https://doi.org/10.3749/canmin.2000032
  49. 49. Gorskaya M.G., Filatov S.K., Rozhdestvenskaya I.V., Vergasova L.P. // Mineral. Mag. 1992. V. 56. P. 411. https://doi.org/10.1180/minmag.1992.056.384.14
  50. 50. Кривовичев С.В., Филатов С.К., Черепанский П.Н. // Записки Рос. минерал. о-ва. 2008. Т. 137. С. 114.
  51. 51. Pekov I.V., Britvin S.N., Agakhanov A.A. et al. // Eur. J. Mineral. 2019. V. 31. P. 1025. https://doi.org/10.1127/ejm/2019/0031-2887
  52. 52. Varaksina T.V., Fundamensky V.S., Filatov S.K., Vergasova L.P. // Mineral. Mag. 1990. V. 54. P. 613. https://doi.org/10.1180/minmag.1990.054.377.14
  53. 53. Effenberger H., Zemann J. // Mineral. Mag. 1984. V. 48. P. 541. https://doi.org/10.1180/minmag.1984.048.349.10
  54. 54. Pertlik F., Zemann J. // Mineral. Petrol. 1988. V. 38. P. 291. https://doi.org/10.1007/BF01167095
  55. 55. Попова В.И., Попов В.А., Рудашевский Н.С. и др. // Записки Всесоюз. минерал. о-ва. 1987. Т. 116. С. 358.
  56. 56. Pekov I.V., Zubkova N.V., Yapaskurt V.O. et al. // Mineral. Petrol. 2023. V. 117. P. 247. https://doi.org/10.1007/s00710-022-00803-0
  57. 57. Pautov L.A., Mirakov M.A., Siidra O.I. et al. // Mineral. Mag. 2020. V. 84. P. 455. https://doi.org/10.1180/mgm.2020.22
  58. 58. Мираков М.А., Паутов Л.А., Сийдра О.И. и др. // Записки Рос. минерал. о-ва. 2023. Т. 152. С. 18. https://doi.org/10.31857/S0869605523010082
  59. 59. Kemp S.J., Rushton J.C., Horstwood M.S.A., Nénert G. // Am. Mineral. 2018. V. 103. P. 1136. https://doi.org/10.2138/am-2018-6194
  60. 60. Fanfani L., Giuseppetti G., Tadini C., Zanazzi P.F. // Mineral. Mag. 1980. V. 43. P. 753. https://doi.org/10.1180/minmag.1980.043.330.08
  61. 61. Pabst A. // Z. Kristallogr. 1934. B. 89. S. 514. https://doi.org/10.1524/zkri.1934.89.1.514
  62. 62. Fanfani L., Nunzi A., Zanazzi P.F., Zanzari A.R. // Mineral. Mag. 1975. V. 40. P. 357. https://doi.org/10.1180/minmag.1975.040.312.04
  63. 63. Avdontceva M.S., Zolotarev A.A., Shablinskii A.P. et al. // Symmetry. 2023. V. 15. P. 1871. https://doi.org/10.3390/sym15101871
  64. 64. Fanfani L., Nunzi A., Zanazzi P.F. et al. // Mineral. Mag. 1975. V. 40. P. 131. https://doi.org/10.1180/minmag.1975.040.310.03
  65. 65. Shi N., Ma Z. // Kexue Tongbao. 1987. V. 32. P. 478. (in Chinese).
  66. 66. Giuseppetti G., Mazzi F., Tadini C. // Neues Jb. Mineral. Mh. 1988. P. 203.
  67. 67. Araki T., Zoltai T. // Am. Mineral. 1973. V. 58. P. 799
  68. 68. Ericksen G.E., Evans H.T., Jr., Mrose M.E. et al. // Am. Mineral. 1989. V. 74. P. 1207.
  69. 69. Пеков И.В., Агаханов А.А., Зубкова Н.В. и др. // Геология и геофизика. 2020. Т. 61. С. 826. https://doi.org/10.15372/GiG2019167
  70. 70. Валяшко М.Г. Геохимические закономерности формирования месторождений калийных солей. М.: Изд-во МГУ, 1962. 397 с.
  71. 71. Бокий Г.Б., Горогоцкая Л.И. // Журн. структур. химии. 1969. Т. 10. С. 624.
  72. 72. Sabelli C., Trosti-Ferroni R. // Periodico Mineral. 1985. V. 54. P. 1.
  73. 73. Расцветаева Р.К., Пущаровский Д.Ю. // Итоги науки и техники. Сер. Кристаллохимия. 1989. Т. 23. 172 с.
  74. 74. Pushcharovsky D.Yu., Lima-de-Faria J., Rastsvetaeva R.K. // Z. Kristallogr. 1998. V. 213. P. 141. https://doi.org/10.1524/zkri.1998.213.3.141
  75. 75. Krivovichev S.V. // Z. Kristallogr. 2008. V. 223. P. 109. https://doi.org/10.1524/zkri.2008.0008
  76. 76. Pekov I.V., Zubkova N.V., Pushcharovsky D.Yu. // Acta Cryst. B. 2018. V. 74. P. 502. https://doi.org/10.1107/S2052520618014403
  77. 77. Лазоряк Б.И. // Успехи химии. 1996. Т. 65. С. 307. https://doi.org/10.1070/RC1996v065n04ABEH000211
  78. 78. Nikolova R., Kostov-Kytin V. // Bulg. Chem. Commun. 2013. V. 45. № 4. P. 418. http://www.bcc.bas.bg/
  79. 79. Dessureault Y., Sangster J., Pelton A.D. // J. Electrochem. Soc. 1990. V. 137. P. 2941. https://doi.org/10.1149/1.2087103
  80. 80. Shchipalkina N.V., Pekov I.V., Britvin S.N. et al. // Can. Mineral. 2021. V. 59. P. 713. https://doi.org/10.3749/canmin.2000105
  81. 81. Shchipalkina N.V., Koshlyakova N.N., Pekov I.V. et al. // Can. J. Mineral. Petrol. 2023. V. 61. P. 609. https://doi.org/10.3749/2200062
  82. 82. Белоусова М.Г., Сапрыкина О.Ю., Бубнова Р.С. и др. // Вулканология и сейсмология. 2021. № 1. С. 57. https://doi.org/10.31857/S0203030620060127
  83. 83. Шорец О.Ю., Филатов С.К., Фирсова В.А., Бубнова Р.С. // Физика и химия стекла. 2021. Т. 47. С. 237. https://doi.org/10.31857/S013266512102013X
  84. 84. Shablinskii A., Bubnova R., Shorets O. et al. // Crystals. 2023. V. 14. Р. 27. https://doi.org/10.3390/cryst14010027
  85. 85. Shablinskii A.P., Filatov S.K., Biryukov Ya. P. // Phys. Chem. Miner. 2023. V. 50. Р. 30. https://doi.org/10.1007/s00269-023-01253-6
QR
Translate