RAS PhysicsКристаллография Crystallography Reports

  • ISSN (Print) 0023-4761
  • ISSN (Online) 3034-5510

DOPING ANTHRACENE CRYSTALS WITH ASSOCIATED IMPURITIES DURING THE GROWTH FROM SOLUTION

PII
S3034551025060186-1
DOI
10.7868/S3034551025060186
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 70 / Issue number 6
Pages
1019-1032
Abstract
The paper presents a study on the effect of aging of solutions on the growth features of anthracene crystals. It was found that prolonged storage (>3 weeks) of saturated solutions in air leads to their aging, accompanied by the precipitation of accompanying yellow needle-shaped crystals alongside the anthracene crystals. The structure of these accompanying needle-shaped crystals was determined by single-crystal X-ray diffraction in the space group P2/c (Z = 4) and was shown to consist of 9,10-anthraquinone molecules. The formation of solid solutions based on co-crystallization of anthracene and 9,10-anthraquinone molecules was not observed. It is shown that the observed long-wavelength shift in the fluorescence spectrum of crystals, which occurs when using certain commercial grades of anthracene for solution growth, is associated with the presence of a homologous impurity–tetracene–in the starting material. The crystallochemical aspects of the incorporation of concomitant impurity molecules into the crystal structure of anthracene are discussed.
Keywords
Date of publication
21.07.2025
Year of publication
2025
Number of purchasers
0
Views
4

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