- PII
- S3034551025060186-1
- DOI
- 10.7868/S3034551025060186
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 70 / Issue number 6
- Pages
- 1019-1032
- Abstract
- The paper presents a study on the effect of aging of solutions on the growth features of anthracene crystals. It was found that prolonged storage (>3 weeks) of saturated solutions in air leads to their aging, accompanied by the precipitation of accompanying yellow needle-shaped crystals alongside the anthracene crystals. The structure of these accompanying needle-shaped crystals was determined by single-crystal X-ray diffraction in the space group P2/c (Z = 4) and was shown to consist of 9,10-anthraquinone molecules. The formation of solid solutions based on co-crystallization of anthracene and 9,10-anthraquinone molecules was not observed. It is shown that the observed long-wavelength shift in the fluorescence spectrum of crystals, which occurs when using certain commercial grades of anthracene for solution growth, is associated with the presence of a homologous impurity–tetracene–in the starting material. The crystallochemical aspects of the incorporation of concomitant impurity molecules into the crystal structure of anthracene are discussed.
- Keywords
- Date of publication
- 21.07.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 4
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