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RAS PhysicsКристаллография Crystallography Reports

  • ISSN (Print) 0023-4761
  • ISSN (Online) 3034-5510

Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6

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PII
10.31857/S0023476124040052-1
DOI
10.31857/S0023476124040052
Publication type
Article
Status
Published
Authors
O. V. Reutova
  • Occupation: Geological Faculty, Department of Crystallography and Crystal Chemistry
  • Affiliation: Lomonosov Moscow State University
Volume/ Edition
Volume 69 / Issue number 4
Pages
597-611
Abstract
Crystals of new structural high-symmetry modification of Cs2HIn(IO3)6, which crystallyzes in sp. gr. R3 with parameters of unit cell a = 11.8999(4), c = 11.6513(5) Å were obtained in hydrothermal conditions. Crystal chemical comparison with triclinic modification the investigated earlier was carried out. Both structures are composed of isolated blocks [In(IO3)6]3–. The new modification belongs to the family of trigonal iodates isostructural to K2Ge(IO3)6 compound. Local symmetry of separated blocks [M(IO3)6] (M = Ge, Ti, Sn, Ga, In and other metals) are analyzed. Structural systematic of iodate families is suggested on the base of comparative crystal chemical analysis. The influence of cation composition and synthesis conditions on symmetry and topology of crystal structures as well as local symmetry of blocks on physical properties of compounds are discussed.
Keywords
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
79

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