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Cesium hydrosulfate phosphate crystals: conductivity and real structure at increasing temperature
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Cesium hydrosulfate phosphate crystals: conductivity and real structure at increasing temperature
Annotation
PII
S0023476125010119-1
Publication type
Article
Status
Published
Authors
R. V. Gainutdinov 
Affiliation: Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics of NRC “Kurchatov institute”
Edition
Volume 70 Issue number 1
Pages
84-89
Abstract
Superprotonic crystals Cs3(HSO4)2(H2PO4) and Cs4(HSO4)3(H2PO4) have been investigated by conducting atomic force microscopy at increasing temperature. Local volt-ampere characteristics have been measured and an increase in conductivity at 413–453 K for Cs3(HSO4)2(H2PO4) and Cs4(HSO4)3(H2PO4) by two and three orders of magnitude, respectively, has been recorded. Differences in the conductive characteristics of crystals of different compositions in the vicinity of the phase transition are shown. Information on topographic and electrical features of crystalline phases before and after exposure to temperature and electric fields has been obtained. The influence of external factors on the stability of the surface microstructure is evaluated. Possible mechanisms of structural-phase transformations of isostructural compounds with different ratio of sulfate and phosphate groups are discussed.
Received
04.04.2025
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References

1. Haile S.M., Boysen D.A., Chisholm C.R.I., Merle R.B. // Nature. 2001. V. 410. P. 910. https://doi.org/10.1038/35073536

2. Pawlaczyk Cz., Pawłowski A., Połomska M. et al. // Phase Transitions. 2010. V. 83. P. 854. http://dx.doi.org/10.1080/01411594.2010.509159

3. Louie M.W., Hightower A., Haile S.M. // ACS Nano. 2010. V. 4. № 5. P. 2811.

4. Paschos O., Kunze J., Stimming U., Maglia F. // J. Phys.: Condens. Matter. 2011. V. 23. P. 234110. http://dx.doi.org/10.1088/0953-8984/23/23/234110

5. Ponomareva V., Lavrova G. // Solid State Electrochem. 2011. V. 15. P. 213. https://doi.org/10.1007/s10008-010-1227-1

6. Dupuis A.-C. // Progress in Materials Science. 2011. V. 56. P. 289. http://dx.doi.org/10.1016/j.pmatsci.2010.11.001

7. Mohammad N., Mohamad A.B., Kadhum A.A.H., Loh K.S. // J. Power Sources. 2016. V. 322. P. 77. https://doi.org/10.1016/j.jpowsour.2016.05.021

8. Aili D., Gao Y., Han J., Li Q. // Solid State Ionics. 2017. V. 306. P. 13. http://dx.doi.org/10.1016/j.ssi.2017.03.012

9. Colomban P. // Solid State Ionics. 2019. V. 334. P. 125. https://www.researchgate.net/publication/331249475

10. Ortiz E., Vargas R.A., Tróchez J.C. et al. // J. Phys. Status Solidi. C. 2007. V. 4. № 11. P. 4070. https://doi.org/10.1002/pssc.200675933

11. Ortiz E., Piñeres I., León C. // J. Therm. Anal. Calorim. 2016. V. 126. P. 407. https://doi.org/10.1007/s10973-016-5474-y

12. Баранов А.И., Синицин В.В., Понятовский Е.Г. и др. // Письма в ЖЭТФ. 1986. Т. 44. Вып. 44. С. 186.

13. Mikheykin A.S., Chernyshov D.Yu., Makarova I.P. et al. // Solid State Ionics. 2017. V. 305. P. 30. https://doi.org/10.1016/j.ssi.2017.04.017

14. Papandrew B., Li Q., Okatan M.B. et al. // Nanoscale. 2015. V. 7. P. 20089. https://doi.org/10.1039/c5nr04809e

15. Kalinin S., Dyck O., Balke N. et al. // ACS Nano. 2019. V. 13. № 9. P. 9735. https://doi.org/10.1021/acsnano.9b02687

16. Kempaiah R., Vasudevamurthy G., Subramanian A. // Nano Energy. 2019. P. 103925. https://doi.org/10.1016/j.nanoen.2019.103925

17. Гайнутдинов Р.В., Толстихина А.Л., Селезнева Е.В., Макарова И.П. // ЖТФ. 2020. № 11. С. 1843. https://doi.org/10.21883/JTF.2020.11.49972.116-20

18. Коморников В.А., Гребенев В.В., Макарова И.П. и др. // Кристаллография. 2016. Т. 61. № 4. С. 645. https://doi.org/10.1134/S1063774516040106

19. Гайнутдинов Р.В., Толстихина А.Л., Селезнева Е.В. и др. // Кристаллография. 2024. Т. 69. № 3. С. 470. https://doi.org/10.31857/S0023476124030129

20. Анкудинов А.В., Гущина Е.В., С.А. Гуревич С.А. и др. // Международный научный журнал “Альтернативная энергетика и экология”. 2008. № 10 (66). С. 30.

21. Гайнутдинов Р.В., Толстихина А.Л., Селезнева Е.В. и др. // Кристаллография. 2023. Т. 68. № 2. С. 290. https://doi.org/10.31857/S0023476123020066

22. Makarova I.P., Isakova N.N., Kalyukanov A.I. et al. // Acta Cryst. B. 2024. V. 80. P. 201. https://doi.org/10.1107/s2052520624003470 Q2

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