RAS PhysicsКристаллография Crystallography Reports

  • ISSN (Print) 0023-4761
  • ISSN (Online) 3034-5510

Crystal chemistry of silver borates with salt-inclusion structures

PII
S0023476125020055-1
DOI
10.31857/S0023476125020055
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 70 / Issue number 2
Pages
281-295
Abstract
A review of structural studies of silver borates with salt-inclusion structures is presented. Data on the first halogen-containing silver borates are provided, along with the structural and physicochemical characterization of the Ag4B4O7X2 (X = Br, I), Ag3B6O10X (X = Br, I, NO3), Ag4B7O12X (X = Cl, Br, I) families, as well as Ag4(B3O6)(NO3) and Ag3B4O6(OH)2(NO3). The crystal structures of these compounds are framework-type, layered, or composed of isolated boron-oxygen groups. In almost all cases, silver atoms exhibit pronounced anharmonicity in thermal displacements, which was investigated using X-ray structural analysis, including extensive temperature-dependent studies. The reasons for the low stability of chlorine-containing silver borates are discussed, along with the relationship between the anharmonicity of thermal displacements and other properties, such as the high ionic conductivity of Ag3B6O10I.
Keywords
Date of publication
15.09.2025
Year of publication
2025
Number of purchasers
0
Views
85

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