Composite Perfluorinated Membranes Modified by Polyvinyl Alcohol Cross-Linked with Sulfosuccinic Acid

Primachenko, O.N.; Marinenko, E.A.; Lebedev, V.T.; Orlova, V.A.; Vavilova, V.D.; Gofman, I.V.; Lezova, O.S.; Klechkovskaya, V.V.; Vlasova, E.N.; Kononova, S.V.

doi:10.7868/S3034551025050054

PII

S30345510S0023476125050054-1

DOI

10.7868/S3034551025050054

Publication type

Article

Status

Published

Authors

O.N. Primachenko

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Institute of Macromolecular Compounds

E.A. Marinenko

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Institute of Macromolecular Compounds

V.T. Lebedev

Affiliation: Neutron Researches Department, Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute”

V.A. Orlova

Affiliation: Khlopin Radium Institute

V.D. Vavilova

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Institute of Macromolecular Compounds

I.V. Gofman

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Institute of Macromolecular Compounds

O.S. Lezova

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Grebenshchikov Institute of Silicate Chemistry

V.V. Klechkovskaya

Affiliation: Shubnikov Institute of Crystallography of the Kurchatov Complex Crystallography and Photonics of the NRC “Kurchatov Institute”

E.N. Vlasova

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Institute of Macromolecular Compounds

S.V. Kononova

Affiliation: Branch of Konstantinov St. Petersburg Nuclear Physics Institute, National Research Centre “Kurchatov Institute” – Institute of Macromolecular Compounds

Volume/ Edition

Volume 70 / Issue number 5

Pages

744-758

Abstract

The effect of polyvinyl alcohol (PVA) cross-linked with sulfosuccinic acid on the structure, morphology, physical, mechanical and electrochemical properties of composite membranes made of domestic perfluorinated copolymer, an analogue of Nafion, and PVA was studied. An increase in the amount of cross-linked PVA in the membrane leads to an increase in proton conductivity. The crystallinity of the composites depends on the proportion of the cross-linking agent. The morphology of the membrane surfaces varies significantly: the lower surface has a uniform microstructure, and the upper surface forms three-dimensional folded structures during self-organization of polymer chains in the surface layer. According to energy-dispersive analysis, the two layers of the membrane differ significantly in chemical composition, which is illustrated by the distribution profiles of fluorine across the membrane thickness. The observed structural and morphological features of the membranes explain the differences in their proton conductivity.

Keywords

Date of publication

03.07.2025

Year of publication

2025

Number of purchasers

Views

References

1. Kusoglu A., Weber A.Z. // Chem. Rev. 2017. V. 117. P. 987. https://doi.org/10.1021/acs.chemrev.6b00159
2. Sigwadi R., Nemavhola F. // Membranes. 2023. V. 13. P. 887. https://doi.org/10.3390/membranes13120887
3. Giancola S., Zaton M., Reyes-Carmona A. et al. // J. Membr. Sci. 2019. V. 570–571. P. 69. https://doi.org/10.1016/j.memsci.2018.09.063
4. Wang H., Zhang J., Ning X. et al. // Int. J. Hydrogen Energy. 2021. V. 46. P. 25225. doi.org/10.1016/j.ijhydene.2021.05.048
5. Chen T., Lv B., Sun S. et al. // Membranes. 2023. V. 13. P. 308. https://doi.org/10.3390/membranes13030308
6. Prykhodko Y., Fatyeyeva K., Hespel L. et al. // Chem. Engin. J. 2021. V. 409. P. 127329. https://doi.org/10.1016/j.cej.2020.127329
7. Gagliardi G.G., Ibrahim A., Borello D. et al. // Molecules. 2020. V. 25. P. 1712. https://doi.org/10.3390/molecules25071712
8. Arslanova A.A., Sanginov E.A., Dobrovol'skii Yu.A. // Rus. J. Electrochem. 2018. V. 54. P. 318. https://doi.org/10.1134/S1023193518030035
9. Ali N., Ali F., Khan S. et al. // J. Mol. Struct. 2021. V. 1231. P. 129940. https://doi.org/10.1016/j.molstruc.2021.129940
10. Boaretti C., Pasquini L., Sood R. et al. // J. Membr. Sci. 2018. V. 545. P. 66. http://dx.doi.org/10.1016/j.memsci.2017.09.055
11. Фалина И.В., Березина Н.П. // Высокомол. соед. Сер. Б. 2010. Т. 52. С. 715.
12. Bolto B., Tran T., Hoang M. et al. // Prog. Polym. Sci. 2009. V. 34. P. 969. https://doi.org/10.1016/j.progpolymsci.2009.05.003
13. Lyozova O.S., Zagrebelny O.A., Krasnopeeva E.L. et al. // Glass Phys. Chem. 2021. V. 47. P. 173. https://doi.org/10.1134/S1087659621020061
14. Lezova O.S., Myasnikov D.V., Shilova O.A. et al. // Int. J. Hydrogen Energy. 2022. V. 47. P. 4846. https://doi.org/10.1016/j.ijhydene.2021.11.158
15. Barbashov V.I., Chaika E.V. // Физика и техника высоких давлений. 2019. Т. 29. С. 116.
16. Barbashov V.I., Chaika E.V. // Физика и техника высоких давлений. 2021. Т. 31. С. 39.
17. Dong F., Xu S., Wu X. et al. // Separ. Purificat. Technol. 2021. V. 267. P. 118629. https://doi.org/10.1016/j.seppur.2021.118629
18. Rhim J., Park H., Lee C. et al. // J. Membr. Sci. 2004. V. 238. P. 143. https://doi.org/10.1016/j.memsci.2004.03.030
19. Rao A.S., Rashmi K.R., Manjunatha D.V. et al. // Mat. Today Proc. 2021. V. 35. P. 344. https://doi.org/10.1016/j.matpr.2020.02.093
20. Molla S., Compan V., Gimenez E. et al. // Int. J. Hydrogen Energy. 2011. V. 36. P. 9886. https://doi.org/10.1016/j.ijhydene.2011.05.074
21. Ivanchev S.S., Likhomanov V.S., Primachenko O.N. et al. // Petr. Chem. 2012. V. 52. P. 453. https://doi.org/10.1134/S0965544112070067
22. Primachenko O.N., Odinokov A.S., Marinenko E.A. et al. // J. Fluor. Chem. 2021. V. 244. P. 109736. https://doi.org/10.1016/j.jfluchem.2021.109736
23. Kim H., Lee S., Kim S. et al. // J. Mater. Sci. 2017. V. 52. P. 2400. https://doi.org/10.1007/s10853-016-0534-z
24. De Bonis C., Cozzi D., Mecheri B. et al. // Electrochim. Acta. 2014. V. 147. P. 418. https://doi.org/10.1016/j.electacta.2014.09.135
25. Сафронова Е.Ю., Воропаева Д.Ю., Новикова С.А. и др. // Мембраны и мембранные технологии. 2022. Т. 12. С. 47. https://doi.org/10.1134/S221811722201007
26. Примаченко О.Н., Кульвелис Ю.В., Лебедев В.Т. и др. // Мембраны и мембранные технологии. 2020. Т. 10. С. 3. https://doi.org/10.1134/S221811722001006X

GOST	Gofman I., Klechkovskaya V., Kononova S., Lebedev V., Lezova O., Marinenko E., Orlova V., Primachenko O., Vavilova V., Vlasova E. Composite Perfluorinated Membranes Modified by Polyvinyl Alcohol Cross-Linked with Sulfosuccinic Acid // Crystallography Reports. – 2025. – V. 70. – Issue number 5 C. 744-758 . URL: https://crystallographyras.ru/s30345510s0023476125050054-1/?version_id=121674. DOI: 10.7868/S3034551025050054
MLA	Gofman, I.V, Klechkovskaya, V.V, Kononova, S.V, Lebedev, V.T, Lezova, O.S, Marinenko, E.A, Orlova, V.A, Primachenko, O.N, Vavilova, V.D, Vlasova, E.N "Composite Perfluorinated Membranes Modified by Polyvinyl Alcohol Cross-Linked with Sulfosuccinic Acid." Crystallography Reports. 70.5 (2025).:744-758. DOI: 10.7868/S3034551025050054
APA	Gofman I., Klechkovskaya V., Kononova S., Lebedev V., Lezova O., Marinenko E., Orlova V., Primachenko O., Vavilova V., Vlasova E. (2025). Composite Perfluorinated Membranes Modified by Polyvinyl Alcohol Cross-Linked with Sulfosuccinic Acid. Crystallography Reports. vol. 70, no. 5, pp.744-758 DOI: 10.7868/S3034551025050054

RAS PhysicsКристаллография Crystallography Reports

Composite Perfluorinated Membranes Modified by Polyvinyl Alcohol Cross-Linked with Sulfosuccinic Acid

You can

References

Indexing

RAS PhysicsКристаллография Crystallography Reports

Composite Perfluorinated Membranes Modified by Polyvinyl Alcohol Cross-Linked with Sulfosuccinic Acid

You can

References

Indexing

Via social network